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Heterogeneous Catalysis in Organic Chemistry

Release on 1999-06-301999-06-30 by Gerard V. Smith
Heterogeneous Catalysis in Organic Chemistry

Author: Gerard V. Smith

Publisher: Academic Press

ISBN: 008052480X

Category: Science

Page: 346

View: 444

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations
Science
Heterogeneous Catalysis in Organic Chemistry
Language: en
Pages: 346

Heterogeneous Catalysis in Organic Chemistry

Authors: Gerard V. Smith, Ferenc Notheisz
Categories: Science
Type: BOOK - Published: 1999-06-30 - Publisher: Academic Press

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents
Catalysis of Organic Reactions
Language: en
Pages: 416

Catalysis of Organic Reactions

Authors: Robert L. Augustine
Categories: Science
Type: BOOK - Published: 2020-09-10 - Publisher: CRC Press

This book provides a complete updating of important developments in the study of catalysis as it applies to organic synthesis — with applications in major industrial processes. It covers a broad variety of catalytic processes — both homogeneous and heterogeneous.
Catalysis of Organic Reactions
Language: en
Pages: 376

Catalysis of Organic Reactions

Authors: Dale W. Blackburn
Categories: Science
Type: BOOK - Published: 2020-07-24 - Publisher: CRC Press

This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.
Catalysis of Organic Reactions
Language: en
Pages: 680

Catalysis of Organic Reactions

Authors: Frank E. Herkes
Categories: Science
Type: BOOK - Published: 1998-08-21 - Publisher: CRC Press

Documents up-to-date developments in the study of catalysis and its applications to organic synthesis and industrial processes. The text examines the area of homogenous and heterogenous catalysis for industrial and pharmaceutical chemicals, focusing on recent advances in asymmetric synthesis, environmental uses, acid-based synthesis, hydrogenation, oxidation, alkylation, isomerization, amination, hydroformlyation, and
Catalysis of Organic Reactions
Language: en
Pages: 600

Catalysis of Organic Reactions

Authors: Jr., John R. Sowa
Categories: Science
Type: BOOK - Published: 2005-03-30 - Publisher: CRC Press

This volume compiles 63 peer-reviewed scientific papers documenting the latest developments in the application of homogeneous, heterogeneous, and immobilized homogenous catalysts used in organic synthesis. Catalysis of Organic Reactions consists of primary research articles accompanied by experimental sections that emphasize chemical processes with

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